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Thermodynamics: An Engineering Approach, 4/e
Yunus A. Çengel, University of Nevada, Reno
Michael A. Boles, North Carolina State University

Properties of Pure Substances

Learning Objectives


I.

Introduce the concept of a pure substance.

II.

Discuss the physics of phase-change processes.

III.

Illustrate the P-v, T-v, and P-T property diagrams and P-v-T surfaces of pure substances.

IV.

Demonstrate the procedures for determining thermodynamic properties of pure substances from tables of property data.

V.

Describe the hypothetical substance "ideal gas" and the ideal-gas equation of state.

VI.

Apply the ideal-gas equation of state in the solution of typical problems.

VII.

Introduce the compressibility factor, which accounts for the deviation of real gases from ideal-gas behavior, and to illustrate its use.

VIII.

Present some of the best-known equations of state such as the van der Waals, Beattie-Bridgeman, and Benedict-Webb-Rubin equations.

IX.

Define the specific heat at constant volume and the specific heat at constant pressure.

X.

Relate the specific heats to the calculation of the changes in internal energy and enthalpy of ideal gases.

XI.

Describe the incompressible substance such as solids and liquids and how to determine the changes in internal energy and enthalpy for these substances.