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Multiple Choice Quiz



1

The major product of the reaction of 1,2-dibromobutane and excess NaNH2 is
A)2-bromo-1-butene.
B)1-bromo-1-butene.
C)1-butyne.
D)1,2-butadiene.
2

Alkynes may be formed directly via elimination from which of the following?
A)alkanes
B)bromoalkenes
C)alcohols
D)alkenes
3

The major product of the reaction of 2,2-dichloropropane and excess NaNH2 is
A)propyne.
B)1,2-propadiene.
C)2-chloropropene.
D)2-chloropropane
4

Which of the following dibromides would yield 2-butyne upon elimination?
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A)III
B)II and III
C)II and IV
D)I
5

Which of the following is the MOST acidic?
A)1-butyne
B)2-butyne
C)1-butene
D)butane
6

Which of the following will produce 4-methyl-1-pentyne?
A)ethyne + 1) NaNH2 2) 1-iodobutane
B)propyne + 1) NaNH2 2) 1-iodopropane
C)ethyne + 1) NaNH2 2) 1-iodo-2-methylpropane
D)propyne + 1) NaNH2 2) 2-iodopropane
7

Predict the product of the following reaction sequence.
ethyne + 1) excess NaNH2 2) excess I–CH2–(CH2)2–CH3
A)6-iodo-1-hexyne
B)1-hexyne
C)5-decyne
D)1-iodo-1-hexene
8

Which of the following anions is the WEAKEST base?
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A)a
B)b
C)c
D)d
9

Which of the following anions is the STRONGEST base?
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A)a
B)b
C)c
D)d
10

Which of the following alkynes reacts with sodium amide?
A)Cyclodecyne
B)2-Pentyne
C)2-Butyne
D)1-Hexyne
11

What is the product of the following reaction?
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A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_5.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_6.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (16.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_7.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (17.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_8.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (17.0K)</a>
12

Predict the product of the reaction of 1-pentyne and excess Br2.
A)1,1-dibromo-1-pentene
B)1,2-dibromo-1-pentene
C)1,1,2,2-tetrabromopentane
D)2,2-dibromo-1-pentene
13

Predict the product of the reaction of 2-pentyne and excess Br2/CCl4.
A)2,3-dibromo-2-pentene
B)2,2-dibromo-3,3-dichloropentane
C)2,3-dichloro-2-pentene
D)2,2,3,3-tetrabromopentane
14

Predict the product of the reaction of 1,4-pentadiyne and excess Cl2.
A)1,1,5,5-tetrachloropentane
B)1,2,4,5-tetrachloro-1,4-pentadiene
C)1,2,4,5-tetrachloropentane
D)1,1,2,2,4,4,5,5-octachloropentane
15

Which product forms when 4-octyne reacts with one equivalent of bromine?
A)(Z)-3,4-Dibromo-3-octene
B)(Z)-3,4-Dibromo-3-octene
C)(E)-4,5-Dibromo-4-octene
D)(Z)-4,5-Dibromo-4-octene
16

Which product is obtained from the reaction of 1-hexyne with excess chlorine?
A)2,2-Dichlorohexane
B)1,2-Dichlorohexane
C)1,2-Dichloro-1-hexene
D)1,1,2,2-Tetrachlorohexane
17

Predict the product of the reaction of 1-pentyne and excess HBr.
A)1,1-dibromopentane
B)1,2-dibromopentane
C)2,2-dibromopentane
D)2-bromo-1-pentene
18

Predict the product of the reaction of 1-pentyne and excess HBr in the presence of hydrogen peroxide.
A)1,1-dibromopentane
B)1,2-dibromopentane
C)2,2-dibromopentane
D)2-bromo-1-pentene
19

Predict the product of the reaction of 1-pentyne and excess HCl in the presence of hydrogen peroxide.
A)1,1-dichloropentane
B)1,2-dichloropentane
C)2,2-dichloropentane
D)2-chloro-1-pentene
20

How many products would be expected from the reaction of 1,5-heptadiyne with excess HCl?
A)1
B)2
C)3
D)4
21

Identify the product of the following reaction.
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A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_9a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (11.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_9b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (11.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_9c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209339/11_9d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>







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