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1 | | What is the product of the following reaction? (15.0K) |
| | A) | (12.0K) |
| | B) | (13.0K) |
| | C) | (12.0K) |
| | D) | (12.0K) |
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2 | | What is the product of the following reaction? (15.0K) |
| | A) | (13.0K) |
| | B) | (15.0K) |
| | C) | (14.0K) |
| | D) | (14.0K) |
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3 | | What is the product of the following reaction? (16.0K) |
| | A) | (14.0K) |
| | B) | (15.0K) |
| | C) | (13.0K) |
| | D) | (15.0K) |
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4 | | What is the product of the reaction of 3-hexyne and O3 followed by acetic acid? |
| | A) | propanoic acid |
| | B) | hexanoic acid |
| | C) | 3,4-hexanediol |
| | D) | 3-hexanone |
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5 | | What is(are) the product(s) of the reaction of 2-hexyne and basic KMnO4 followed by acidic workup? |
| | A) | ethyne and butyne |
| | B) | ethanol and 1-butanol |
| | C) | ethanoic acid and butanoic acid |
| | D) | 2,3-hexanediol |
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6 | | What product(s) is(are) obtained when 2-butyne is treated under ozonolysis conditions? |
| | A) | (10.0K) |
| | B) | (12.0K) |
| | C) | (10.0K) |
| | D) | (12.0K) |
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7 | | Which of the following are products of the ozonolysis (O3 in CH2Cl2) of 1,6-decadiyne? (28.0K) |
| | A) | a, e, i |
| | B) | g, h |
| | C) | b, c |
| | D) | d, f |
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8 | | How many compounds are formed upon ozonolysis of the following triyne? (14.0K) |
| | A) | 2 |
| | B) | 3 |
| | C) | 4 |
| | D) | 5 |
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9 | | What is the correct name of the following compound? (14.0K) |
| | A) | 3-methylbenzoic acid |
| | B) | m-methylbenzoate |
| | C) | tolylcarboxylate |
| | D) | methylbenzoate |
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10 | | Rank the following compounds in order of increasing acidity? Hint: Less acidic < < most acidic. (24.0K) |
| | A) | 1 < 2 < 3 < 4 |
| | B) | 2 < 4 < 1 < 3 |
| | C) | 4 < 1 < 3 < 2 |
| | D) | 3 < 4 < 1 < 2 |
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11 | | Which of the following compounds is the most acidic?
CH3COOH H2SO4 CH3OH
HF |
| | A) | CH3COOH |
| | B) | H2SO4 |
| | C) | CH3OH |
| | D) | HF |
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12 | | The correct IUPAC name for acid A is (14.0K) |
| | A) | 4,4-dimethyl-3-hexanoic acid |
| | B) | 3-(1,1-dimethylpropyl)butanoic acid |
| | C) | 3,3-dimethyl-2-ethylpentanoic acid |
| | D) | 2-ethyl-3,3-dimethylpentanoic acid |
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13 | | Place the following compounds in order from strongest acid to weakest acid. (17.0K) |
| | A) | a > b > c > d |
| | B) | d > c > b > a |
| | C) | d > b > c > a |
| | D) | a > c > b > d |
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14 | | Place the following compounds in order from strongest acid to weakest acid. (6.0K) |
| | A) | a > d > c > b |
| | B) | c > a > d > b |
| | C) | c > d > b > a |
| | D) | a > d > b > d |
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15 | | Which of the following compounds does NOT give benzoic acid when heated with alkaline potassium permanganate? |
| | A) | tert-butylbenzene |
| | B) | ethylbenzene |
| | C) | toluene |
| | D) | styrene |
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16 | | What is the product of the following synthesis? (18.0K) |
| | A) | (13.0K) |
| | B) | (14.0K) |
| | C) | (15.0K) |
| | D) | (14.0K) |
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17 | | What is the product of the following synthesis? (16.0K) |
| | A) | (12.0K) |
| | B) | (11.0K) |
| | C) | (10.0K) |
| | D) | (13.0K) |
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18 | | What is the product of the following synthesis? (18.0K) |
| | A) | (14.0K) |
| | B) | (15.0K) |
| | C) | (15.0K) |
| | D) | (13.0K) |
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19 | | Which of the following is the only naturally occurring amino acid with the R configuration at the α-carbonyl stereogenic center? |
| | A) | serine |
| | B) | arginine |
| | C) | cysteine |
| | D) | proline |
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20 | | What is the major structure of aspartic acid present at pH = 7 in aqueous solution?
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| | A) | (14.0K) |
| | B) | (14.0K) |
| | C) | (14.0K) |
| | D) | (14.0K) |
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21 | | What is the major structure of glycine present at pH = 1 in aqueous solution? |
| | A) | (12.0K) |
| | B) | (12.0K) |
| | C) | (12.0K) |
| | D) | (13.0K) |
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22 | | Based on the pKa values given, which of the following statements regarding alanine is FALSE? (25.0K) |
| | A) | Alanine is a stronger acid than propanoic acid. |
| | B) | The isoelectric point of alanine is 6.0. |
| | C) | At the isoelectric point, alanine exists primarily as the dipolar zwitterion ion. |
| | D) | At pH 12, alanine is uncharged. |
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23 | | Which of the following amino acids has pI ~ 9.8? |
| | A) | (23.0K) |
| | B) | (22.0K) |
| | C) | (23.0K) |
| | D) | (20.0K) |
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24 | | Which of the following structures is called a zwitterion? |
| | A) | (2.0K) |
| | B) | (2.0K) |
| | C) | (2.0K) |
| | D) | (2.0K) |
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