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1 |  |  What is the product of the following reaction?
 (15.0K) |
|  | A) |  (12.0K) |
|  | B) |  (13.0K) |
|  | C) |  (12.0K) |
|  | D) |  (12.0K) |
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2 |  |  What is the product of the following reaction?
 (15.0K) |
|  | A) |  (13.0K) |
|  | B) |  (15.0K) |
|  | C) |  (14.0K) |
|  | D) |  (14.0K) |
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3 |  |  What is the product of the following reaction?
 (16.0K) |
|  | A) |  (14.0K) |
|  | B) |  (15.0K) |
|  | C) |  (13.0K) |
|  | D) |  (15.0K) |
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4 |  |  What is the product of the reaction of 3-hexyne and O3 followed by acetic acid? |
|  | A) | propanoic acid |
|  | B) | hexanoic acid |
|  | C) | 3,4-hexanediol |
|  | D) | 3-hexanone |
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5 |  |  What is(are) the product(s) of the reaction of 2-hexyne and basic KMnO4 followed by acidic workup? |
|  | A) | ethyne and butyne |
|  | B) | ethanol and 1-butanol |
|  | C) | ethanoic acid and butanoic acid |
|  | D) | 2,3-hexanediol |
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6 |  |  What product(s) is(are) obtained when 2-butyne is treated under ozonolysis conditions? |
|  | A) |  (10.0K) |
|  | B) |  (12.0K) |
|  | C) |  (10.0K) |
|  | D) |  (12.0K) |
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7 |  |  Which of the following are products of the ozonolysis (O3 in CH2Cl2) of 1,6-decadiyne?
 (28.0K) |
|  | A) | a, e, i |
|  | B) | g, h |
|  | C) | b, c |
|  | D) | d, f |
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8 |  |  How many compounds are formed upon ozonolysis of the following triyne?
 (14.0K) |
|  | A) | 2 |
|  | B) | 3 |
|  | C) | 4 |
|  | D) | 5 |
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9 |  |  What is the correct name of the following compound?
 (14.0K) |
|  | A) | 3-methylbenzoic acid |
|  | B) | m-methylbenzoate |
|  | C) | tolylcarboxylate |
|  | D) | methylbenzoate |
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10 |  |  Rank the following compounds in order of increasing acidity? Hint: Less acidic < < most acidic.
 (24.0K) |
|  | A) | 1 < 2 < 3 < 4 |
|  | B) | 2 < 4 < 1 < 3 |
|  | C) | 4 < 1 < 3 < 2 |
|  | D) | 3 < 4 < 1 < 2 |
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11 |  |  Which of the following compounds is the most acidic?
CH3COOH H2SO4 CH3OH
HF |
|  | A) | CH3COOH |
|  | B) | H2SO4 |
|  | C) | CH3OH |
|  | D) | HF |
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12 |  |  The correct IUPAC name for acid A is
 (14.0K) |
|  | A) | 4,4-dimethyl-3-hexanoic acid |
|  | B) | 3-(1,1-dimethylpropyl)butanoic acid |
|  | C) | 3,3-dimethyl-2-ethylpentanoic acid |
|  | D) | 2-ethyl-3,3-dimethylpentanoic acid |
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13 |  |  Place the following compounds in order from strongest acid to weakest acid.
 (17.0K) |
|  | A) | a > b > c > d |
|  | B) | d > c > b > a |
|  | C) | d > b > c > a |
|  | D) | a > c > b > d |
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14 |  |  Place the following compounds in order from strongest acid to weakest acid.
 (6.0K) |
|  | A) | a > d > c > b |
|  | B) | c > a > d > b |
|  | C) | c > d > b > a |
|  | D) | a > d > b > d |
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15 |  |  Which of the following compounds does NOT give benzoic acid when heated with alkaline potassium permanganate? |
|  | A) | tert-butylbenzene |
|  | B) | ethylbenzene |
|  | C) | toluene |
|  | D) | styrene |
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16 |  |  What is the product of the following synthesis?
 (18.0K) |
|  | A) |  (13.0K) |
|  | B) |  (14.0K) |
|  | C) |  (15.0K) |
|  | D) |  (14.0K) |
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17 |  |  What is the product of the following synthesis?
 (16.0K) |
|  | A) |  (12.0K) |
|  | B) |  (11.0K) |
|  | C) |  (10.0K) |
|  | D) |  (13.0K) |
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18 |  |  What is the product of the following synthesis?
 (18.0K) |
|  | A) |  (14.0K) |
|  | B) |  (15.0K) |
|  | C) |  (15.0K) |
|  | D) |  (13.0K) |
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19 |  |  Which of the following is the only naturally occurring amino acid with the R configuration at the α-carbonyl stereogenic center? |
|  | A) | serine |
|  | B) | arginine |
|  | C) | cysteine |
|  | D) | proline |
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20 |  |  What is the major structure of aspartic acid present at pH = 7 in aqueous solution?
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|  | A) |  (14.0K) |
|  | B) |  (14.0K) |
|  | C) |  (14.0K) |
|  | D) |  (14.0K) |
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21 |  |  What is the major structure of glycine present at pH = 1 in aqueous solution? |
|  | A) |  (12.0K) |
|  | B) |  (12.0K) |
|  | C) |  (12.0K) |
|  | D) |  (13.0K) |
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22 |  |  Based on the pKa values given, which of the following statements regarding alanine is FALSE?
 (25.0K) |
|  | A) | Alanine is a stronger acid than propanoic acid. |
|  | B) | The isoelectric point of alanine is 6.0. |
|  | C) | At the isoelectric point, alanine exists primarily as the dipolar zwitterion ion. |
|  | D) | At pH 12, alanine is uncharged. |
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23 |  |  Which of the following amino acids has pI ~ 9.8? |
|  | A) |  (23.0K) |
|  | B) |  (22.0K) |
|  | C) |  (23.0K) |
|  | D) |  (20.0K) |
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24 |  |  Which of the following structures is called a zwitterion? |
|  | A) |  (2.0K) |
|  | B) |  (2.0K) |
|  | C) |  (2.0K) |
|  | D) |  (2.0K) |
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