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1 |  |  What is the product of the following reaction?
 (14.0K) |
|  | A) |  (16.0K) |
|  | B) |  (17.0K) |
|  | C) |  (17.0K) |
|  | D) |  (16.0K) |
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2 |  |  What is the major product of the following reaction?
 (12.0K) |
|  | A) |  (14.0K) |
|  | B) |  (14.0K) |
|  | C) |  (14.0K) |
|  | D) |  (14.0K) |
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3 |  |  What is the starting material used in the following reaction?
 (16.0K) |
|  | A) |  (13.0K) |
|  | B) |  (14.0K) |
|  | C) |  (13.0K) |
|  | D) |  (14.0K) |
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4 |  |  Which of the following compounds is the product of an aldol condensation reaction?
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|  | A) |  (12.0K) |
|  | B) |  (13.0K) |
|  | C) |  (13.0K) |
|  | D) |  (12.0K) |
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5 |  |  Which of the following aldehydes is required to make compound A?
 (18.0K) |
|  | A) | phenylethanal |
|  | B) | 2-phenylpropanal |
|  | C) | benzaldehyde |
|  | D) | 2-phenylbutanal |
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6 |  |  What is the major product of the following reaction?
 (14.0K) |
|  | A) |  (14.0K) |
|  | B) |  (14.0K) |
|  | C) |  (13.0K) |
|  | D) |  (13.0K) |
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7 |  |  What is the major product of the following reaction?
 (15.0K) |
|  | A) |  (15.0K) |
|  | B) |  (17.0K) |
|  | C) |  (15.0K) |
|  | D) |  (15.0K) |
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8 |  |  Predict the product of the following reaction:
 (15.0K) |
|  | A) |  (12.0K) |
|  | B) |  (13.0K) |
|  | C) |  (11.0K) |
|  | D) |  (13.0K) |
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9 |  |  What two components, when treated with NaOEt in ethanol, would NOT give a successful crossed aldol reaction? |
|  | A) | acetaldehyde and acetone |
|  | B) | formaldehyde and acetone |
|  | C) | benzaldehyde and acetone |
|  | D) | 2,4-pentanedione and acetone |
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10 |  |  What is the major product of the following reaction?
 (15.0K) |
|  | A) |  (14.0K) |
|  | B) |  (14.0K) |
|  | C) |  (15.0K) |
|  | D) |  (17.0K) |
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11 |  |  Which of the following is NOT the product of an intramolecular aldol condensation? |
|  | A) |  (15.0K) |
|  | B) |  (12.0K) |
|  | C) |  (16.0K) |
|  | D) |  (15.0K) |
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12 |  |  Which product(s) should be formed in the following reaction?
 (13.0K)
 (16.0K) |
|  | A) | a and b |
|  | B) | a, b, and c |
|  | C) | c and d |
|  | D) | c only |
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13 |  |  Which is the major product of the following reaction?
 (13.0K)
 (16.0K) |
|  | A) | a |
|  | B) | b |
|  | C) | c |
|  | D) | d |
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14 |  |  What is the major product of the following reaction?
 (15.0K) |
|  | A) |  (16.0K) |
|  | B) |  (15.0K) |
|  | C) |  (16.0K) |
|  | D) |  (15.0K) |
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15 |  |  Which of the following compounds is not the product of a Robinson annulation reaction? |
|  | A) |  (13.0K) |
|  | B) |  (14.0K) |
|  | C) |  (14.0K) |
|  | D) |  (15.0K) |
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16 |  |  What are the products of the following synthesis?
 (16.0K) |
|  | A) |  (16.0K) |
|  | B) |  (14.0K) |
|  | C) |  (15.0K) |
|  | D) |  (15.0K) |
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17 |  |  What two components can be used to prepare the following compound using the Robinson annulation reaction?
 (14.0K) |
|  | A) |  (13.0K) |
|  | B) |  (13.0K) |
|  | C) |  (14.0K) |
|  | D) |  (14.0K) |
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18 |  |  Which of the following compounds is NOT a reasonable substrate for the Claisen condensation reaction? |
|  | A) |  (12.0K) |
|  | B) |  (12.0K) |
|  | C) |  (13.0K) |
|  | D) |  (13.0K) |
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19 |  |  Which reaction will give the following product?
 (14.0K) |
|  | A) |  (13.0K) |
|  | B) |  (14.0K) |
|  | C) |  (14.0K) |
|  | D) |  (14.0K) |
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20 |  |  Which ester will give the following product when treated with MeONa?
 (14.0K) |
|  | A) |  (12.0K) |
|  | B) |  (13.0K) |
|  | C) |  (13.0K) |
|  | D) |  (13.0K) |
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21 |  |  What starting material would be required to synthesize the following compound via a Claisen condensation reaction?
 (12.0K) |
|  | A) | methyl acetate |
|  | B) | ethyl acetate |
|  | C) | ethyl formate |
|  | D) | 3-pentanone |
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22 |  |  Is it possible to synthesize the following compound via a Claisen condensation reaction? If so, what would the starting material be?
 (13.0K) |
|  | A) | No, it is not possible to synthesize this material via a Claisen condensation. |
|  | B) | Yes, if you start with ethyl propanoate. |
|  | C) | Yes, if you start with ethyl butanoate. |
|  | D) | Yes, if you start with ethyl 2-methylpentanoate. |
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23 |  |  Which of the following compounds will condense with ethyl acetate in the presence of sodium ethoxide to give
 (13.0K) |
|  | A) |  (14.0K) |
|  | B) |  (13.0K) |
|  | C) |  (13.0K) |
|  | D) |  (13.0K) |
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24 |  |  Which of the following comounds will NOT undergo a Michael reaction with a 1,3-ketoester enolate? |
|  | A) |  (11.0K) |
|  | B) |  (12.0K) |
|  | C) |  (11.0K) |
|  | D) |  (13.0K) |
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25 |  |  What is the product of the following synthesis?
 (19.0K) |
|  | A) |  (10.0K) |
|  | B) |  (13.0K) |
|  | C) |  (15.0K) |
|  | D) |  (15.0K) |
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26 |  |  A Michael reaction is an example of a conjugate addition. What is a conjugate addition? |
|  | A) | A conjugate addition is a synchronous addition of an electrophile and nucleophile to a double bond. |
|  | B) | A conjugate addition is a nucleophilic addition to a triple bond followed by protonation. |
|  | C) | A conjugate addition converts an α,β-unsaturated ketone into a substituted saturated ketone. |
|  | D) | A conjugate addition is a nucleophilic addition to an aromatic ring followed by expulsion of a leaving group. |
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27 |  |  Which if the following compounds is NOT a Michael acceptor? |
|  | A) |  (12.0K) |
|  | B) |  (11.0K) |
|  | C) |  (11.0K) |
|  | D) |  (11.0K) |
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28 |  |  Which of the following compounds does NOT serve as an acceptor in a Michael reaction?
 (19.0K) |
|  | A) | a |
|  | B) | b |
|  | C) | c |
|  | D) | d |
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