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1 | | What is the product of the following reaction? (14.0K) |
| | A) | (16.0K) |
| | B) | (17.0K) |
| | C) | (17.0K) |
| | D) | (16.0K) |
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2 | | What is the major product of the following reaction? (12.0K) |
| | A) | (14.0K) |
| | B) | (14.0K) |
| | C) | (14.0K) |
| | D) | (14.0K) |
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3 | | What is the starting material used in the following reaction? (16.0K) |
| | A) | (13.0K) |
| | B) | (14.0K) |
| | C) | (13.0K) |
| | D) | (14.0K) |
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4 | | Which of the following compounds is the product of an aldol condensation reaction?
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| | A) | (12.0K) |
| | B) | (13.0K) |
| | C) | (13.0K) |
| | D) | (12.0K) |
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5 | | Which of the following aldehydes is required to make compound A? (18.0K) |
| | A) | phenylethanal |
| | B) | 2-phenylpropanal |
| | C) | benzaldehyde |
| | D) | 2-phenylbutanal |
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6 | | What is the major product of the following reaction? (14.0K) |
| | A) | (14.0K) |
| | B) | (14.0K) |
| | C) | (13.0K) |
| | D) | (13.0K) |
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7 | | What is the major product of the following reaction? (15.0K) |
| | A) | (15.0K) |
| | B) | (17.0K) |
| | C) | (15.0K) |
| | D) | (15.0K) |
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8 | | Predict the product of the following reaction: (15.0K) |
| | A) | (12.0K) |
| | B) | (13.0K) |
| | C) | (11.0K) |
| | D) | (13.0K) |
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9 | | What two components, when treated with NaOEt in ethanol, would NOT give a successful crossed aldol reaction? |
| | A) | acetaldehyde and acetone |
| | B) | formaldehyde and acetone |
| | C) | benzaldehyde and acetone |
| | D) | 2,4-pentanedione and acetone |
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10 | | What is the major product of the following reaction? (15.0K) |
| | A) | (14.0K) |
| | B) | (14.0K) |
| | C) | (15.0K) |
| | D) | (17.0K) |
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11 | | Which of the following is NOT the product of an intramolecular aldol condensation? |
| | A) | (15.0K) |
| | B) | (12.0K) |
| | C) | (16.0K) |
| | D) | (15.0K) |
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12 | | Which product(s) should be formed in the following reaction? (13.0K) (16.0K) |
| | A) | a and b |
| | B) | a, b, and c |
| | C) | c and d |
| | D) | c only |
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13 | | Which is the major product of the following reaction? (13.0K) (16.0K) |
| | A) | a |
| | B) | b |
| | C) | c |
| | D) | d |
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14 | | What is the major product of the following reaction? (15.0K) |
| | A) | (16.0K) |
| | B) | (15.0K) |
| | C) | (16.0K) |
| | D) | (15.0K) |
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15 | | Which of the following compounds is not the product of a Robinson annulation reaction? |
| | A) | (13.0K) |
| | B) | (14.0K) |
| | C) | (14.0K) |
| | D) | (15.0K) |
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16 | | What are the products of the following synthesis? (16.0K) |
| | A) | (16.0K) |
| | B) | (14.0K) |
| | C) | (15.0K) |
| | D) | (15.0K) |
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17 | | What two components can be used to prepare the following compound using the Robinson annulation reaction? (14.0K) |
| | A) | (13.0K) |
| | B) | (13.0K) |
| | C) | (14.0K) |
| | D) | (14.0K) |
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18 | | Which of the following compounds is NOT a reasonable substrate for the Claisen condensation reaction? |
| | A) | (12.0K) |
| | B) | (12.0K) |
| | C) | (13.0K) |
| | D) | (13.0K) |
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19 | | Which reaction will give the following product? (14.0K) |
| | A) | (13.0K) |
| | B) | (14.0K) |
| | C) | (14.0K) |
| | D) | (14.0K) |
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20 | | Which ester will give the following product when treated with MeONa? (14.0K) |
| | A) | (12.0K) |
| | B) | (13.0K) |
| | C) | (13.0K) |
| | D) | (13.0K) |
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21 | | What starting material would be required to synthesize the following compound via a Claisen condensation reaction? (12.0K) |
| | A) | methyl acetate |
| | B) | ethyl acetate |
| | C) | ethyl formate |
| | D) | 3-pentanone |
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22 | | Is it possible to synthesize the following compound via a Claisen condensation reaction? If so, what would the starting material be? (13.0K) |
| | A) | No, it is not possible to synthesize this material via a Claisen condensation. |
| | B) | Yes, if you start with ethyl propanoate. |
| | C) | Yes, if you start with ethyl butanoate. |
| | D) | Yes, if you start with ethyl 2-methylpentanoate. |
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23 | | Which of the following compounds will condense with ethyl acetate in the presence of sodium ethoxide to give (13.0K) |
| | A) | (14.0K) |
| | B) | (13.0K) |
| | C) | (13.0K) |
| | D) | (13.0K) |
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24 | | Which of the following comounds will NOT undergo a Michael reaction with a 1,3-ketoester enolate? |
| | A) | (11.0K) |
| | B) | (12.0K) |
| | C) | (11.0K) |
| | D) | (13.0K) |
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25 | | What is the product of the following synthesis? (19.0K) |
| | A) | (10.0K) |
| | B) | (13.0K) |
| | C) | (15.0K) |
| | D) | (15.0K) |
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26 | | A Michael reaction is an example of a conjugate addition. What is a conjugate addition? |
| | A) | A conjugate addition is a synchronous addition of an electrophile and nucleophile to a double bond. |
| | B) | A conjugate addition is a nucleophilic addition to a triple bond followed by protonation. |
| | C) | A conjugate addition converts an α,β-unsaturated ketone into a substituted saturated ketone. |
| | D) | A conjugate addition is a nucleophilic addition to an aromatic ring followed by expulsion of a leaving group. |
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27 | | Which if the following compounds is NOT a Michael acceptor? |
| | A) | (12.0K) |
| | B) | (11.0K) |
| | C) | (11.0K) |
| | D) | (11.0K) |
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28 | | Which of the following compounds does NOT serve as an acceptor in a Michael reaction? (19.0K) |
| | A) | a |
| | B) | b |
| | C) | c |
| | D) | d |
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