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Multiple Choice
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1

An exothermic process:
A)raises the temperature of one gram of a substance by one degree Celsius.
B)takes in heat from the surroundings
C)increases the acidity of the surroundings
D)gives off heat to the surroundings
E)releases carbon dioxide into the surroundings
2

Calculate the amount of heat necessary to raise the temperature of 8.5 kg of water from 12.5°C to 84°C
A)2.99 x 103 kJ
B)35.56 J
C)2.54 x 103 kJ
D)2.54 x 106 kJ
E)254 kJ
3

How many calories are required to heat 4.5 g of water from 23 to 85.0 °C
A)383 cal
B)104 cal
C)243 cal
D)279 cal
4

Consider the following exothermic reaction, the rate law at 298 K is: Rate = k [H2] [I2] ----------- H2(g) + I2(g) --> 2 HI(g) Addition of a catalyst would effect the initial rate of the reaction by:
A)increasing the initial rate of the forward reaction
B)increasing the initial rate of both forward and reverse reactions
C)increasing the initial rate of the reverse reaction
D)causing no increase or decrease in the rate of reaction
E)none of the above
5

Below is the reaction profile for the reaction of (C2H4) with (C4H6).

<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=gif:: ::/sites/dl/free/0072920033/80712/image93.gif','popWin', 'width=480,height=267,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (19.0K)</a>

Your best estimate for the enthalpy of reaction ()Hrxn) is:

A)+115 kJ/mol
B)-287 kJ/mol
C)+287 kJ/mol
D)-172 kJ/mol
E)+172 kJ/mol
6

What is the correct equilibrium expression for the following reaction? 2NO2(g) ---> 2NO(g) +O2(g)
A)Keq = [O2]2[NO]/[NO2]2
B)Keq = [O2][NO]2/[2NO2]2
C)Keq = [NO2]2/[NO]2[O2]
D)Keq = [NO2]2/[NO][O2]2
E)None of the above
7

Which of the following factors will cause the equilibrium 2NOBr(g) ---> 2NO(g) + Br2(g) , H = -47.3 kJ/mol to be shifted to the left (in favor of reactants)?
A)Some Ar(g) is added to increase the total pressure in the vessel
B)NOBr(g) is added
C)A catalyst is added
D)The volume of the container is increased to double times its original volume
E)The temperature is increased
8

Which of the following factors will cause the equilibrium H2(g) + I2(g) ---> 2HI(g) , H = +15 kJ/mol to be shifted to the left (in favor of reactants)?
A)HI(g) is removed.
B)I2(g) is added
C)Some N2(g) is added to increase the pressure in the vessel
D)The volume of the container is reduced to half of its original volume
E)The temperature is decreased
9

K is a constant for a certain reaction, but if _____ changes, K will change.
A)Pressure
B)Time
C)Volume
D)Temperature
E)Concentration
10

Which of the following has the greatest entropy per mole?
A)ice
B)water
C)steam
D)all have the same entropy, because all three are H2O







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